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PFA Technical Data

Fluoropolymer Comparison

Fluoropolymer Comparison - Typical Properties

The values shown represent average experiences from numerous testing sources and are not intended to be specifications.

Mechanical Properties

Property

ASTM Standard

 

Unit


PTFE

 

FEP

 

PFA

 

ETFE

Specific Gravity

D792

 --

2.15

2.15

2.15

1.76

Tensile Strength

D1457

D1708

D638

MPa

(psi)

21-34

(3,000-5,000)

23

(3,400)

25

(3,600)

40-46

(5,800-6,700)

Elongation

D1457

D1708

D638

%

300-500

325

300

150-300

Flexural Modulus

D790

MPa

(psi)

496

(72,000)

586

(85,000)

586

(85,000)

1,172

(170,000)

Folding Endurance

D2176

(MIT)

cycles

>106

5-80 x 103

10-500 x 103

10-27 x 103

Impact Strength

D256

J/m

(ft·lb/in)

189

(3.5)

No Break

No Break

No Break

Hardness

D2240

Shore D pencil

50-65 HB

56
HB

60

72

Coefficient of Friction, Dynamic

D1894

--

0.05-0.10

0.08-0.3

--

0.3-0.4

 

Thermal Properties

Property

ASTM Standard

 

Unit


PTFE

 

FEP

 

PFA

 

ETFE

Melting Point

D3418

°C

(°F)

327

(621)

260

(500)

306

(582)

267

(512)

Cure
Temperature

--

°C

(°F)

379-429

(715-805)

360-385

(680-725)

379-399

(715-750)

302-323

(575-615)

Flame Rating*

UL94

--

V0

V0

V0

V0

Limiting Oxygen Index

D2863

%

>95

>95

>95

30-36

Heat of Combustion

D240

MJ/kg

(Btu/lb)

5.1

(2,200)

5.1

(2,200)

5.3

(2,300)

13.7

(5,900)

* Statements regarding behavior in a flame situation are not intended to reflect hazards presented by this or any other material when under actual fire conditions.

 

Chemical Properties

Property

ASTM Standard

 

Unit


PTFE

 

FEP

PFA

 

ETFE

Chemical/Solvent Resistance

D543

  --

Excellent

Excellent

Excellent

Excellent

Water Absorption, 24 h

D570

%

<0.01

<0.01

<0.03

<0.03

Salt Spray Resistance (1)
-on aluminum
-on steel

B-117

 
Hours
Hours

 
744+
192

 
744+
--

 
1000
--

 
1000
--

Detergent Resistance (2)
-on aluminum
-on grit-blasted aluminum
-on grit-blasted steel

-- 

 
Hours
Hours
Hours

 
264
624
24

 
744
600
480

 
--
--
--

 
--
--
--

Weather Resistance

Florida Exposure

Years Unaffected

20

20

10

15

Notes:

1. Salt Spray Resistance: 5% NaCl at 35°C/95°F, hours to failure
2. Detergent Resistance: hours to failure

 

Electrical Properties

Property

ASTM Standard

 

Unit

 

PTFE

 

FEP

PFA

 

ETFE

Dielectric Constant

D150

1 MHz

2.1

2.1

2.1

2.6

Dielectic Strength*

D149

V/µm

18

53

80

79

Dissipation Factor

D150

1 MHz

<0.0001

0.0006

0.0001

0.007

Arc Resistance

D495

sec

>300

300

>180

122

Volume Resistivity

D257

ohm·cm

>1018

>1018

>1018

>1017

Surface Resistivity

D257

ohm/sq

>1018

>1016

>1017

>1015

* Dielectric Strength: 100 micrometers film

 

Vapor Transmission Rates

Vapor Transmission Rates of FEP Film, 25 µm (1 mil) thickness/per ASTM E-96 (modified)
Values measured on thicker specimens and converted to 25 µm (1 mil)

 

Vapor

Temperature, °C

g/100 sq in. or g/625 sq cm (24 hr)

Acetic Acid

35

0.41

Acetone

35

0.95

Acetophenone

25

0.50

Benzene

35

0.64

Carbon Tetrachloride

35

0.31

Etyl Acetate

35

0.76

Hexane

35

0.56

Hydrochloric Acid, 20%

25

<0.01

Piperidine

25

0.04

Red Fuming Nitric Acid

25

7.5-1.4

Sodium Hydroxide, 50%

25

<0.01

Sulfuric Acid, 98%

25

0.00001

Water

39.5

0.40

 

 

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Last Update: August 17, 2007
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